That only makes sense if you wanted to store relational data in a NoSQL database (and that's not what Mongo is meant to do)
The way you use the term implies that you're referring to the type of data, but the term generally refers to the method used for storing the data.
This distinction is important because it leads to a circular reasoning dynamic: many of us are accustomed to storing the data in tabular form using a relational data model. But choosing to use that particular model to represent objects or entities or ideas does not make those objects or entities or ideas fundamentally relational data.
Because PostgreSQL is unacceptably poor at HA/replication compared to MongoDB.