> There are some roundabout ways to try to measure this, but it seems much easier to just charge people for driving at peak hours.
Agreed: there's no reason why they shouldn't say that e.g. key bridges, interchanges, etc. are EZ-Pass only with a toll during rush hour. These days, we should have the infrastructure to simply have a camera record license plates and mail a monthly bill to you.
Around here (Washington DC) it'd be a huge win if all of the suburban commuters stopped their commute at a subway / bus station rather than attempting to drive the last 3 miles into the very congested downtown (my walking speed is higher than the average traffic speed at 8am). Simply putting a toll point at the bridge would be a great way to encourage that last step not to be a single-occupant vehicle.
The other, major win would be to stop subsidizing parking below market rates: city parking is usually cheaper than the commercial lots, which means a significant amount of congestion is caused by drivers slowing looking around for cheaper parking. Making that savings less dramatic would encourage people to simply park at the first available space.