"Preposition" is already something of an unnatural word class. They have two main functions in English: to describe some kind of location ("Sam? He's with Natasha"), and to mark certain arguments to verbs ("The tools? Sam's playing with them").
It's just a coincidence that prepositions serve both of these purposes in English; in Mandarin, the same two purposes are served by completely separate word classes. Verb argument markers are preposed; location markers are postposed.