Sorry to be pedantic, but most US businesses have 208/120V or 480/277V three-phase electrical services. There are some old existing 240/120V three-phase high-leg delta (aka bastard leg) delta services. [0] Delta-wye transformers are the most common type today, that’s where you get the 208/120 and 480/277 services from. [1]
Larger commercial/industrial customers can have their own medium/high voltage substations and premises wiring/distribution.
Medium voltage is 2.4kV to 70kV with 4160V and 13800V being the most common for commercial/industrial applications. High voltage is roughly 100kV to 1mV.