I don't think the UK will try to join anytime soon, but the EU would be silly to not accept them back. The UK is already Europe's second biggest economy, and depending on how Germany goes, could be the biggest in a couple of decade. It has the biggest tech industry in Europe by quite a bit, a relatively healthy demography, a solid military, bases across the world, soft power _galore_).
Like, grudges and personal issues aside, the numbers say the EU would be greatly bolstered with the UK in it.