However, I'm not sure it'd be effective: the whole problem with tailgaters is that they follow too closely, so there might not be enough space for the chaff to decelerate and trigger the tailgater's radar. It would be an interesting test, though. But I think an active radar emitter that detects the tailgater's radar and generates a matching signal that appears like a rapidly-braking car would be better, though obviously more technically difficult.
I'm sure the best way to not run into other cars on the road is to detect the other objects that are also moving at non-zero velocities. They're likely to be other cars, rather than road signs, poles, etc.
If they wouldn’t do that filtering they would trigger a brake for almost all manhole covers and overhead signs and such.
Also a dopler radar can scan the whole sector with every emission, and simply measure the distance to the closest moving objects (and their speed) with each scan.
A radar that creates a 2d image of the sector usually needs to send a targeted beam in one direction at a time. Such a radar is not only much more expensive, it also adds latency.
Visible light is better suited for 2D imaging, anyway.
I guess it my be better to stick with old-fashioned caltrops instead of chaff.