In Classical Euclidean Geometry there are five axioms, and while the first four seem clear and obvious, the fifth seems a little contrived. So for centuries people tried to prove that the fifth was unnecessary and could be proven from the other four.
These attempts all failed, and we can show that they must fail, because there are systems that satisfy the first four, but do not satisfy the fifth. Hence the fifth cannot be a consequence of the first four. Such systems are (for obvious reasons) called Non-Euclidean Geometries.
So we can use explicit examples to demonstrate that certain proofs are impossible, and the Banach-Tarski Theorem is a result that proves that a "Measure"[0] cannot have all four obviously desirable characteristics.
For more information, here's a blog post[1] I wrote some time ago:
https://www.solipsys.co.uk/new/ThePointOfTheBanachTarskiTheo...
It's intended to be readable, but the topic is inherently complex, so it may need more than one read through. If you're interested.
[0] Technical term for a function that takes an object and returns a concept of its size. For lines it's length, for planar objects it's area, for 3D objects it's volume, and so on.
[1] In case people want to discuss that separately I've submitted it as a separate post here: https://news.ycombinator.com/item?id=40798224