Usernames have lower entropy than a random salt and are predictable in many cases. People re-use usernames and some usernames are common. If your password system became common on the web, or if I knew the workings of your password system (i.e. open source / leaked codebase / Kerckhoffs's principle[1]), I could generate a rainbow table for either common or targeted users. This means I could generate a rainbow table for "Jabbles", gain access to your password and compromise your account before the website is likely even aware of a breach or has time to warn you. Salts only act to slow down, not prevent, compromising leaked password hashes (as you can always brute force which is quite practical with MD5/SHA1). Thus, using a username defeats one of the stated purposes of salting.
It's also said ad nauseam (with good reason) but rolling your own in security is a bad idea, especially when libraries exist that do exactly what you'd intend to do just as easily. Algorithms such as bcrypt and scrypt exist and are well vetted. bcrypt is easy to integrate with many languages and provides a trivial interface and sane defaults for iterations/rounds [brute force] and salts [rainbow table]. bcrypt can also handle increasing the security of your system over time as the metadata is stored as part of the hash.
tl;dr Using a username for salting means a targeted attack against a single or small number of users would be damn near impossible to stop as the second they have the password hashes they also have the passwords.