The Part Design wall thickness tool works but is not good.
But in 0.22-dev there is a good sketch offset/sketch frame tool that would let you make an outline wall in 2D that you can then pocket.
Another approach is to make a SubshapeBinder of a face, offset that and pocket it directly.
Fillets and chamfers work but they have OCC bugs and limitations; there are ways to work around them but whereas in Fusion360 you might place geometry on a chamfer, with anything built around OCC it is better to treat chamfers and fillets as “dress-up” only, and do them last. Anything structural is definitely better done in a sketch or with a subtractive sweep on an edge.
Bosses: you can taper pads/extrudes easily enough, and there are some tricks involving copying external geometry of sketches and face/shape binders that can help you match them up across bodies.
None of this is to suggest that FreeCAD is easier than Fusion360. It’s not, and it’s definitely something of a lifestyle choice. (You won’t hear me telling you that you should use GIMP over Photoshop, though).
But it also doesn’t have Fusion360’s limitations: ten or five projects or whatever at a time, reapplying for the license every year, STEP support that could get taken away from you again when Autodesk decides to reassess the free tier, etc.; and I can share FreeCAD as easily as I can share my designs.
Don’t get me wrong, I don’t think Fusion360 is bad or Autodesk is a particularly unusually bad actor. I just don’t want to be dependent on the whims of closed source free tiers in cloud software until I absolutely have to be.
So far, my limitations in CAD have nothing to do with FreeCAD, and my 3D printer isn’t the slowest part of the puzzle. In both cases the issue is me.
The problem of the “right way” is definitely FreeCAD’s primary issue; it’s not as easy to mix the guided flow of Part Design with the more generalised tools in the other workbenches as it should be. (Sketches on curved surfaces are a classic example of this.)
But there is an increasingly broad range of tutorial materials out there now, and the major changes around Ondsel and FreeCAD 1.0 will only improve things.