Commerce with software goods, or even exchange for digital traditional currencies, suffers from exactly the same problem as physical goods: there is no possible way to use the block chain to guarantee that a payment on the block chain will result in a good or service being provided outside the block chain. You can try to build more things onto the block chain itself, but that quickly becomes un scalable.
And for elections: if you think for a second that a crypto voting machine wouldn't have been cast doubt on by the people who brought you "Hugo Chavez stole the election through Dominion voting machines", then I have no idea on what planet you live.
On a separate topic, the USA is almost uniquely bad in the world, at least for rich democratic countries, in having such problems carrying out elections.
In my own, incomparably poorer, country, with a 50% rural population, we just don't have these problems. You have a 90% physical voting system: you come to the polling station, they check your ID in an electronic system to make sure you meet the voting age and haven't voted before in this election, they give you a stamp and a ballot, you stamp the ballot in a private booth, typically in a local school. You fold the ballot, and put it in a big urn. At the end of the voting day, representatives of all parties and anyone else who registered as an observer opens the urn and they all count the votes. They report the counts higher up electronically, and safely store the physical ballots. Elections happen on a Sunday, from 8 AM to 8 PM, sometimes with local extensions where a polling station is still full at the close. Preliminary results from exit polls are announced immediately at 8PM by the media. The electoral officials announce the first official preliminary results by 22PM, and then throughout the night. By 12 PM the next day, the vote count and official final results are typically out.
No "hanging chads", etc. There are plenty of other electoral issues (busing, paying for votes, strong local cliques where even representatives of different parties conspire to steal votes for a single party, bad education leading to people not knowing their rights or who to vote for, etc). But not procedural problems, and no machines that make it easy to hide systematic stealing.