I would find even a statement from Signal like "we can't access our users content" to be tenuous and overly-optimistic. Like, when I heard the word "can't" my brain goes to: there is nothing anyone in the company could do, within the bounds of the law, to do this. Employees at Slack could turn off the technical measures preventing this from occurring. Employees at Signal could push an app update which side-channels all messages through to a different server, unencrypted.
Better phrasing is "Employees of Slack will not access the underlying content".