In the November 2023 list, Aurora was also in second place, with an Rmax of 585.34 PetaFLOPS/second.
See https://www.top500.org/system/180183/ for the specs on Aurora, and https://www.top500.org/system/180047/ for the specs on Frontier.
See https://www.top500.org/project/top500_description/ and https://www.top500.org/project/linpack/ for a description of Rmax and the LINPACK benchmark, by which supercomputers are generally ranked. The Top 500 list only includes supercomputers that are able to run the LINPACK benchmark, and where the owner is willing to publish the results.
The jump in Aurora's Rmax scope is explained by Aurora's difficult birth. https://morethanmoore.substack.com/p/5-years-late-only-2 (published when the November 2023 list came out) has a good explanation of what's been going on.