pi^(n/2)/fact(n/2)
which behaves very interestingly[1]. It's equal to pi in two dimensions, peaks at the 4-dimensional ball (about 1.6 pi), then is driven to effectively zero by the time you get to 20 dimensions or so (value of ~8/1000 pi).Again, however, the radius isn't changing. I don't think of unit balls as being spiky--they're still rotationally invariant in all d rotational degrees of freedom, so calling them spiky doesn't sit well with me.
Instead, imagine you lived on a line, only walking up and back along it forever. Then, one day, someone introduced you to the plane and then a volume. These are vastly larger than the space you were afforded by the line: exponential blowup.
It's also driven home by how the Lesbegue measure in d-dimensions assigns zero measure to all (d-1)-dimensional (or lesser) objects. Adding a dimension just makes space immensely larger.
And so pegging the size of our unit ball to its 1-dimensional parameter, the radius, causes its volume to vanish.
[1] Wolfram Alpha chart showing the volume of the n-sphere in units of pi http://www.wolframalpha.com/input/?i=pi%5E%28n%2F2-1%29%2FGa...