https://www.aceee.org/greener-cars#1 on the Greener Cars list.
Running the math, its clear that ACEEE assumes you're 100% Electric. According to brief Reddit searches, it seems like Prius Prime 2024 is closer to 75% electric / 25% gasoline in practice. (You could *theoretically* stay in 100% electric mode since its just one button click... but 11-second 0-to-60 time is pretty bad, so many people prefer to be in Hybrid mode instead)
That's still quite good though. And if you've got a lot of city driving (ex: 0-to-30 times), then 100% EV mode button is probably pleasurable. But if you have a highway or two as your commute, you'll want the ICE engine part of Prius Prime to get you up to speed.
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Still, Prius Prime is incredibly efficient. In 100% gas mode, it still scores 64 Green Score due to its lack of rare-earth metals in its EV motors, its smaller 13.6kW-hr battery pack (less Lithium/Cobalt being mines), and far lighter weight than most EVs. And at 130+ MPGe, its going to use less electricity than most EVs (even highly efficient ones like Leaf).
So all in all, Prius Prime is likely the most environmentally friendly vehicle you can buy in practice (even after correcting ACEEE's mistake of 100% EV assumption on this vehicle).
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The only real downside is that most drivers don't plan to use the PHEV part, and instead focus on the Hybrid part. At which point, the Corolla Hybrid or Crown Hybrids are better vehicles.