You could certainly offer to pay someone for electricity from their home or business, but then you're parked in their driveway for a period of time waiting. And the social aspects of this make it a lot more challenging than simply walking up to the local blacksmith and buying a gallon or two of solvent off the shelf so you can get to the next town.
You're at that point relying on the kindness of strangers.
On the other hand, I've had the "I noticed an external outlet near my parking spot, do you mind if I plug my car into it while I shop/stay at this hotel/eat at this restaurant?" conversation plenty of times and there's no "challenge" to it nor "transaction". The most common answer I've got has been "I don't see why not" because it's not really a transaction for most businesses, whatever extra they spend on electricity they easily make back in making a new customer or keeping an existing customer happy. In a few times I got back "there's a Level 2 charger hidden at the Library across the street and the fees support our local library" or "we have a deal with this parking garage a block away that has chargers and we can validate your parking for you when you get back", which just goes to show how normalized it already can often be as just another "parking consideration" of "where to park" when you ask businesses about it. Most businesses are used to answering "is there a good place to park?" questions. Parking is normal operations for a business, not "relying on the kindness of strangers". Electricity is "just" an amenity of parking, already in some businesses' minds. (Not enough businesses yet, sure, but more than you might think.)
To be fair, I've never been in a "life or death" situation where a "No" would have been some terrible catastrophe, but I've also never known anyone in my lifetime that had to buy gasoline from a small town Blacksmith or Pharmacist either.