Most functions aren't doing any syscall at all, and as such they aren't either blocking or non-blocking.
Now because of path dependency and because we've been using blocking functions like regular functions, we're accustomed to think that blocking is “normal”, but that's actually a source of bugs as I mentioned before. In reality, async functions are more “normal” than regular functions: they don't do anything fancy, they just return a value when you call them, and what they return is a future/promise. In fact you don't even need to use any async anotation for a function to be async in Rust, this is an async function:
fn toto() -> impl Future<Output = String>> {
unimplemented!();
}
The async keyword exists simply so that the compiler knows it has to desugar the await inside the function into a state machine. But since Rust has async blocks it doesn't even need async on functions at all, the information you need comes from the type of the return value, that is a future.Blocking functions, on the contrary, are utterly bizarre. In fact, you cannot make one yourself, you must either call another blocking function[1] or do a system call on your own using inline assembly. Blocking functions are the anomaly, but many people miss that because they've lived with them long enough to accept them as normal.
[1] because blockingness is contagious, unlike asynchronousness which must be propagated manually, yes ironically people criticizing async/await get this one backward too