240.0.0.0/4 could conceivably be assigned. It's not really in use as it was actually reserved for "future use" from the beginning. That said, if you want to use that space publicly in any reliably usable form you've still got to convince near the entire internet to update their stuff to support/allow it. On this front I'm actually kind of against opening it up even just for internal use as it'd just create another headache to check for and not be particularly reliable. For "extra internal space" 0.0.0.0/8 was in a similar situation and already opened up. If that's not enough for you then you desperately need to move on from IPv4 already.