Tell us more about this scenario. You’re positing a situation where due to an inability to accept cashless payments, supermarkets refuse to sell food to people for an extended period, leading to mass unrest? In the UK?
The UK power grid is remarkably resilient. To the extent that a half hour long power outage in London over 20 years ago is considered notable enough to deserve a Wikipedia article [1]
An extended power outage affecting access to payment capabilities across a large region would be an emergency but it wouldn’t collapse civilization. There’s little reason to suspect people would not find some way to transact while power is restored.