Once it's complete, make it authoritative. Any mention of undefined behavior should be required to reference the corresponding item in the UB annex.
That said, my overall point is that optimization does not rely on undefined behavior at all. It's commonly argued that it does, but there are languages without undefined behavior that have working optimizers, so it's clearly false. Some optimizations for C (and C++) currently depend on undefined behavior, but there's nothing inherent about that dependence.