If Michael Jackson rose from the dead to host the Olympics opening ceremony and there were 2B tweets/second about it, then postgres on a single server isn't going to scale.
A crud app with 5-digit requests/second? It can do that. I'm sure it can do a lot more, but I've only ever played with performance tuning on weak hardware.
Visa is apparently capable of a 5-digit transaction throughput ("more than 65,000")[0] for a sense of what kind of system reaches even that scale. Their average throughput is more like 9k transctions/second[1].
[0] https://usa.visa.com/solutions/crypto/deep-dive-on-solana.ht...
[1] PDF. 276.3B/year ~ 8.8k/s: https://usa.visa.com/dam/VCOM/global/about-visa/documents/ab...