Dangerous chemicals found in recycled plastics, making them unsafe for use
theconversation.com
theconversation.com
My own wife dumps non-compostable stuff in the compost all the time, is annoyed at me when I point it out, and then somehow doesn't think twice about taking the free compost for gardening.
Interested in health to avoid an entire societal ecosystem, but not enough to test their own soil, even once.
Can you explain more? I'm not familiar with this crowd. Takes care of what?
Then you use it for soil and eat it
https://anh-usa.org/wp-content/uploads/2023/06/230621-ANH-US...
Using it for food sounds like a bad idea.
https://www.epa.gov/sites/default/files/2019-12/documents/ep...
All kinds of shit goes into the storm water drains, including a bunch of Teflon's relatives.
On the rare occasions that they test a field for PFAS, it often comes up positive. I think it's just "don't ask, don't tell" at this point.
(Edit: Ok, maybe it's "only" 5% of farmland: https://www.ewg.org/news-insights/news/2022/04/ewg-forever-c... )
I mean, maybe I shouldn't be that hard on them -- you do need to reuse human and animal waste if you want to be sustainable, and this is a plausible way to do that, and they weren't thinking about PFAS at the time (only PCBs are mentioned in that document) -- but it should be obvious now that the current sewage system is not compatible with this use case. Too many nasty things can get into it. Which does create a problem -- if you don't apply the sludge, then what do you do with it? It's like we need a whole separate system for only organic waste. Or we have to stop selling to the public -- or to industry -- any compound we're not willing to eat.
But does it matter? Food touches plastic throughout the preparation phase. Most factories have plentiful plastic components. Workers have plastic gloves. Then the final product is wrapped in plastic.
Removing it from feed wouldn’t do much in terms of exposure.
I get that the plastics industry has an interest in making recycling appear seamless and efficient, but what a crock.
† The very easiest is steel which you just sort with magnets, but aluminium is more valuable and it's not that hard for machines to sort it, paper/ board can often be machine sorted too.
PET recycling is the one exception, where you can relatively reliably get reasonable (but lower) quality plastics back out of the process.
I introduced the majority of plastic in my garden trough expensive earth & compost.
I only use Coco at this point (what is crazy considering there are no coconuts where I live)
But welcome to our reality where we complained about micro plastics so long without doing something that you cannot actually buy earth/compost without macro plastic anymore.
Obviously, labeling things "Recyclable" satisfies an intense emotional need for many people. Regardless of where the stuff they dump into their "Recycling" bins actually ends up.
But at what point would it actually be better - for both the environment and human health - to invent a clean (~no toxic outputs) and efficient-ish way to burn mixed plastic waste as fuel, and to just use that?
Looks like they're still around: https://www.agilyx.com/
https://pubs.acs.org/doi/10.1021/acssuschemeng.1c08400
The pyrolysis route they are using can be problematic because it produces carcinogenic aromatic compounds like
https://en.wikipedia.org/wiki/Benzopyrene
which has a metabolite which is almost a cancer-causing drug. In principle you could pyrolyze plastics all the way down to carbon monoxide + hydrogen syngas and then build that up to molecules you want with C1 chemistry
https://en.wikipedia.org/wiki/C1_chemistry
but most of the people who are trying chemical recycling by pyrolysis are trying to cook the molecules partially so the output fuel is a witches brew rich in hazardous aromatics. There is a lot of research into cleaner processes for chemical recycling such as
https://www.nature.com/articles/s41598-021-83659-2
and that one at the top but every large scale plant I've seen is a pyrolysis plant that's had to fight with environmentalists to start operations. From the viewpoint of a chemical engineer making fuel is for the birds because gasoline costs 50 cents a pound and (almost) any other chemical costs a lot more than that.
Wow. The paper from 2022 so surely noone is using this process yet, but are there any plans to? Any idea if it's practical? For expanded polystyrene?
The gap between the bench and a commercial factory is immense and there are many areas where people write papers like this for decades but nothing really gets built. I think the usual excuse is that the factory is large enough that it needs to gather waste over a huge area and that transportation of EPS is prohibitively expensive. It doesn't help that styrene monomer is worth only 50 cents a pound, about the same as gasoline.
It should be possible for relatively incompetent consumers to tell at a glance precisely which plastic something is made of and figure out how to sort all of their recyclable plastic waste into 2 or 3 categories.
* * *
Or at a higher level, there should be some people with significant systems thinking training doing full society-wide audits of the sources and treatment of materials including plastics, and then regulators should be making targeted policy to fix harms (whether environmental, human health, economic, ...), starting with the most significant ones and working their way down from there.
Do you honestly think that would be sufficient? I expect you'd get significant amounts of the wrong material in all the bins.
If there were 2 types of plastic packaging and they were very obviously visually distinct, it would be much easier for anyone involved in the process to sort them (whether at home or at a recycling plant) compared to the current system with hundreds of distinct types of often visually indistinguishable mixed-material packaging much of which we can't do anything with except chuck it in a landfill.
Is there a burn-temperature above which everything dangerous is basically rendered inert?
I.e., you make stuff so hot that whatever survives is perma-bonded to oxygen, carbon, chlorine, fluorine, etc., and has almost zero chance of reacting with living creatures?
(Ignoring radioactive stuff, I mean.)
https://en.wikipedia.org/wiki/Plasma_gasification
you need to clean up the syngas to get rid of dioxins with a charcoal filter or something like that. The plasma torch is supposed to convert the organic materials in municipal waste (e.g. food waste, plastic, wood) to syngas and then vitrify the remainder as glass particles that trap toxic heavy metals (you could use it as a material for roads and buildings.) Allegedly you can burn the syngas to make enough electricity to run the torch and still sell some to the grid. I guess you'd want to try to capture mercury before it goes up the stack.
They built a few small (like 5 MW) plants to test the idea but attempts to scale up to 50 MW. For a long time the technology belonged to one of Westinghouse's ghosts (like the one that owns the AP1000) but they are still ordering AP1000s but nobody is ordering plasma torches for municipal waste.
https://en.wikipedia.org/wiki/Plasma_gasification_commercial...
These are definitely large scale, large area systems and there have been some engineering problems. A few seem to be operating successfully. Even if the net energy production is zero that's better than it being negative. Financing has been a problem also. It still produces CO2 also, so there is that to consider. It greatly reduces hazards in the waste stream though, so it seems better than a landfill. I'm not sure it would be a good idea to turn the glass plus heavy metals that is produced into building or road materials.
I don't know a ton about this, but it looks like plasma gasification plants achieve something like this -- producing syngas (mostly H, CO), metal nodules, and a slag material (which seems to roughly be, "igneous rocks or sand, but man made"). I'm curious about the composition of the output products. But it seems to usually be net-energy-positive. This seems like a good intro:
https://science.howstuffworks.com/environmental/energy/plasm...
Sci-fi:
I wonder if there are methods from physics that could be used (even if not now cost effectively) to more thoroughly isolate the various elements rather than having the (it seems not totally understood?) chemical reaction of the various components of the plasma as it cools? Like a big industrial scale mass spectrometer? Like the cyclotron scheme to separate isotopes of uranium in the Manhattan Project? Then you could know, "all the lead is in this beam over here" and "all the mercury is in this beam over here", and so on... That'd be neat. Have some plasma physicists working on recycling instead of on fusion...
(At this point I Google more...)
Interesting, so here they separate copper from zinc using a plasma centrifuge:
https://www.sciencedirect.com/science/article/abs/pii/016858...
And here they're looking (hypothetically) at using plasma separation to isolate the component elements in old NdFeB magnets, to recycle them:
https://www.sciencedirect.com/science/article/abs/pii/S09596...
Hmm...
Most cities only have a few collection spots. It would make way more sense to try to separate the trash at the trash location than asking millions of individual people to try to do it correctly, 30% of which can't do it correctly, 30% of which don't care. I'm not sure I've ever seen a single trash can that has 100% of the correct trash in it, even at a FAANMG company that claims to hire the best and brightest.
Then you get ambiguous things like plastic coated paper, marked with a recycle symbol. Or cardboard milk cartons with a plastic cap and plastic infused cardboard (or is it wax?)
Sure, maybe you're supposed to cut the cap part out but lots of people don't know, can't be bothered, won't do it.
If you want this to actually be effective you really need to do it in as few places as possible, the trash collection companies, where a few inspectors can make sure it's being done correctly and a few reporters can check
I'd like to see a world where if you're not sure, it should go in a pile that gets shipped back to the manufacturer... On their dime if labeling standards weren't met, on your dime if they were.
This would give manufacturers a reason to build things in a way where they want the discarded thing back (like how they do with toner cartridges).
I suppose your comment is more of a moan against what you perceive to be "the elite"'s (the rich, the media, the Davos class, etc) fearmongering, but hey, we're not designed to survive infinitely anyway...
[1] https://www.bbc.com/future/article/20230103-how-plastic-is-g...
All available information sources are full of bullshit and conflicting information too, so good luck quantifying any of the available information on hazards.
Frankly, ignoring it all and just living a reasonable life with reasonably low processed foods seems about right though.
If we accept non-scaleable methods then household chickens are great. They keep pets away from gardens, it reduce the need to cut grass, and they are much better than composts. Naturally this method is limited to people who own a house and have garden/outdoor area that is suitable, and where local government allows it.
An other great but non-scalable method is to eat anything that is invasive or which population is a major threat to bio diversity, assuming one do not cultivate or raise it. There are some obvious risk of perverse incentives, but it can be utilized to benefit the environment when done right.
Our ability to identify things that might shorten our lifespan has far outpaced our ability to apply that knowledge usefully. For most of human history you ate what you could and hoped it didn't kill you in a few weeks. It was only relatively recently we even had the capability of discussing things like long term cancer risk or what not.
There’s a tshirt idea
(That is not to say the article is wrong, or that recycling is perfect, just that certain facts in isolation don’t really allow you to draw any conclusions.)
https://en.wikipedia.org/wiki/Bisphenol_A
which was developed as an estrogen active drug until they found this stuff
https://en.wikipedia.org/wiki/Diethylstilbestrol
which worked "better"
Plastic for use in food packaging ought to be regulated as to what you put in it, which ought to be easy for virgin plastic (though seemingly it isn't) but would be much harder if you were recycling plastic meant for different uses.
(Of course there is a lot of controversy about the mobility of plastic components. We know the carcinogenic styrene monomer exists in significant amounts in polystyrene, what's not so clear is how much of it migrates out)
> BPA was never used as a drug.
BPA wasn't developed as a drug, it was developed for it's resin properties.
Oh, fantasic!
Concentration matters and chemical detection methods are so sensitive (ppb) that without reporting how much was found in the plastic, this information is almost useless. That they didn't report concentrations is problematic.
The base study/publication is here, but I didn't see much concentration information there either.
https://www.sciencedirect.com/science/article/pii/S235234092...
There are naturally occurring carcinogens in things like coffee.
But we don’t worry because the amount is so low.
Not sure why bananas became the benchmark! Banana for scale?
I mean sure the article is citing peer-reviewed research but on the other hand and all, but HN thinks nobody has ever heard “the dose makes the poison” before, so maybe pollution is actually fine???
hold up, science, here comes americas smartest boy!
See also, “aha but what about [confounding factor that is super obvious and the paper already discusses controlling for]!”. Like at some point it’s just dismissive to the point of insulting to imply that nobody else has bothered to put minimal thought into something that probably represents person-years of work with the involvement of multiple subject-matter experts and peers.
the covid threads here etc were absolutely insufferable with this, and generally any pollution thread you will get some dork who’s obnoxious enough to pull “the dose makes the poison” on 2,4,7,8-TCDD or whatever - yes, it happened last week!
Look out EPA, here comes Americas smartest boy! /young sheldon adjusts bowtie
in particular with pollution and other things though it’s just gross because it’s so obviously an industry-centric spin that is designed to imply that pollution is generally ok and that there’s no real need for polluters to ever control pollution of any kind because hey, big ocean out there etc. The implication is, again, that nobody else could ever have thought of a lower limit before, and it really plays into the urge a lot of people have to be Americas Smartest Boy in discussions, even when it’s wildly inappropriate in general (like the 2,4,7,8-TCDD example). You can be the smart guy making the clever point in the debate if you just follow this simple talking point, brought to you by SmogCo!
Climate change threads are always lousy with it too. Aha but what about heat island, sun cycles, whatever. Yeah the climate scientists know already, Mr Boy. If you thought of it in five minutes then definitely one of the professionals studying in the field has raised the issue sometime over the last 100 years. And of course the obvious answer you’re proposing is… keep “studying” for decades to solve some minor quibble, and naturally to allow smogco to continue polluting in the meantime?
It’s obnoxious how many companies are throwing recycled plastics into consumer goods (watch bands, hats, phone cases, some clothes even) with no regard to health consequences.
I’m all about being better for the environment but I also don't want to be wearing plastic.
I don't care how expensive some types of plastics are: we should only allow companies to produce safe, recyclable plastics and not let them poison the earth just so that they can make a few basis points of more profit.
Maybe it's time to restrict/forbid their usage, like has been done for other products and chemicals that have turned out unhealthy and/or dangerous although highly profitable. (Asbestos, CFCs, leaded gas, tobacco, [...])
https://www.cbsnews.com/news/plastic-recycling-failed-concep...
Aluminium and glass are more economical to recycle than sourcing virgin materials! comparably simple and infinitely recyclable - and yet we still can't get that right - Plastic is expensive and complex to recycle, the idea that recycling it was ever a solution to plastic pollution is complete BS, there will always be a significant quantity that ends up in the ground and in the sea.
Yes, economics of recycling plastic are very bad, I wonder how high the cost of landfill would need to increase to make it more expensive than recycling.
Compared to other widely used materials that are essentially inert, the environmental cost of not recycling is mostly limited to the impact of sourcing virgin materials that could have been from recycled sources.
Bluesign and Oeko-tex certifications test for BPA. You can find recycled polyester without this (if you have kids, Hanna Andersson's polyester lines claim to be BPA and PFAS free, most Cat and Jack clothing is Oeko-tex certified and Mamavation puts out good information on PFAS in things like children's clothing, backpacks, lunch kits [3]).
1. https://pubmed.ncbi.nlm.nih.gov/33313651/
2. https://www.forbes.com/sites/ariannajohnson/2023/05/18/worri...
But what does this degradation do when these dangerous adulterants are trapped inside of plastics?
Burn it for energy in place of another fossil fuel.
Option 1, burn it:
Plastic burned release energy roughly equivalent to fossil fuels. Therefore, burning it displaces an equal amount of fossil fuels.
Option 2: landfill it
You still fossil energy so you produce it, but producing it is very energy intensive.
Also you now have a landfill filled with a molecular sponge absorbing toxins, breaking up into microscopic pieces and releasing the toxins elsewhere.
> The environment minister Therese Coffey told the Commons: "In environmental terms, it is generally better to bury plastic than to burn it."
Another nasty property is that some chemicals used to make plastic soft or change other properties (additives) often don't chemically bind with it and they leak out over time.
"Recycled" could probably be removed from the title. Plastic and its additives are very likely bad for you period. "A path towards safer reuse of plastics" is missing a more useful point: reduce single use plastic and replace if other materials make more sense for the use-case. Sure, there a many points we could improved regarding to the usage cycle but some problems are just inherent to the current set of plastics.
I try to avoid plastic as much as possible, especially for food or beverages (even more important if hot).
It's sad that such a useful and versatile group of material also has so many downsides.