On the other hand, I could name quite a few people who went the other way, like Urban Dictionary who run on our http://postgres.heroku.com service, too. (I don't normally name customers, but he recorded a video saying he liked us so I think it's fair game. http://success.heroku.com/urbandictionary )
Also contrary to the norm here, some applications last a long time. The one I work with daily is actually 20 years old this year. In that time a lot has changed and in the next 20 years a lot will as well. It makes sense for long-lived applications to plan well ahead and consider paradigm and architecture changes.
This platform started in C++ on OS/2 with Oracle running on VAX/VMS at the back end. It went to Java/J2EE with an Oracle back end in the early 00's. It's now SQL Server and .Net.