>IPv6's awful adoption rate
40+% adoption rate since the World IPv6 Launch Day in 2012 is not what I would call awful [0].
>extend the IPv4 scheme with additional octets?
To clarify, IPv6 and IPv4 addresses are effectively just a number. On Linux, you can even do `ping 16843009` and see the tool actually pinging the address 1.1.1.1! The octets you see in typical IPv4 addresses, or the hextets in IPv6 ones, are just a way to represent those addresses.
If you think the address representation is the main thing holding IPv6 back, you are thinking it wrong. The most likely reason is actually software & hardware support, and the industry's general sentiment of "if it ain't broken, don't fix it" keeping NATs alive.
>seems it would be easier for people to use
The ship has already sailed. If IPv4 addresses are really that easy to remember, DNS would not have been invented.
Furthermore, when it comes to memorization of IPv6 addresses it's very helpful to split them into two halves. The second half can change rather arbitrarily (to maintain privacy by preventing address tracking), but the first half often won't because it is assigned to you by the ISP.
[0]: https://www.google.com/intl/en/ipv6/statistics.html