Just as seeing underscores/asterisks is understood as "the author is emphasizing despite lack of formatting," seeing a leading at sign is understood as "the author is saying 'this word is a username' despite lack of ping."
Same with Outlook, now when you @-someone it highlights them and even adds their address "To".
Just because HN doesn't currently support this syntax, doesn't mean we must not use it. As with the other examples, if enough people do it, I wouldn't be surprised if support is added later.
Thankfully, my username is pretty unique (like yours), and I can easily search for references to me, but if my name was a common word it would be really frustrating trying to weed out references to me, compared to where people are actually referencing me.
People have been reinventing this syntax here for a long time. It has remained useless here for a long time. There is no groundswell of rebellion opportunity. You’ll just have to send an email.
Same as in you profile you can view your own comments (and others) , scanning the message for an @ symbol and checking for a valid username I wouldn't consider to be a major undertaking.
As I said in my comment, searching for @username vs username is much easier already.
But yes, a third party could do it. Perhaps @dangrossman (yes, I did that) may be interested.