Was it Facebook that used someone's photo of themselves in an advert - claiming that it fell under "we can use your images for any purpose" ?
An advertiser once, against the FB terms of service, used a user's profile picture in their advertising. The advertiser was banned from the platform. Here's a news story that might jog your memory on this: http://mashable.com/2009/07/17/facebook-dating-ads-2/