There are only several properties that can be easily distinguised from coins without complex digital processing: weight (and its distribution), sizes, conduction and ferromagnetism.
I suspect US quarters would have the same makeup
Otoh, there are coin mechanisms that can check for and reject quarter sized objects that are attracted to magnets; they might not be installed everywhere that takes US quarters, but if an operator starts getting a nuisance amount of CA quarters, they will be. See this doc [1] for a description of a pretty discerning mechanism (although it accepts both US and CA quarters, a slightly different design could reject CA quarters)
[1] http://segalandassociates.com/Documents/Coin-Mechanisms_Slug...
A coin drops at a known speed and the right coin will get pulled by the right amount by a magnet or get rejected.
If you have a silver coin or a small piece of copper pipe and a large, strong neodymium magnet, then you can easily observe this effect at home by putting the metal sample on a table and quickly waving the magnet past it as close as you can without touching it. The metal will slide across the table following the magnet, despite the metal itself not being magnetic, because the moving magnet induces eddy currents which temporarily create a magnetic field like an electromagnet. Other metals besides silver and copper exhibit weaker responses due to higher electrical resistivity.
TD Bank in Canada had coin counting machines for customers for a while. I dumped a few hundred $ in and was very happy when it kicked back some silver coins to me.
How nice of them!
I had thought pennies were made of zinc towards the end but that was only for a couple years. Then they were made of steel which should be magnetic.
Also, I'm sure you realize, but the US has had dollar coins since at least 1971. The public never really had much interest in using them and with cash use declining, I wouldnt expect that to change.
Nobody wants to carry change, so of course they favour the bill rather than the coin.
Canadians didn’t have much interest in carrying the toonie either, but had no choice in the matter.