Would covering a desert in solar panels cause more thermal solar absorption in that area than would otherwise happen? Yes.
But if we're optimizing for "offsetting the heating effect of human GHG emissions", then installing 4.5TW of solar (about 4x what has been installed worldwide to date) would have a much more positive effect.
The world currently has 1.1TW of solar installed, producing about 6% of all electricity. So our new installation would be on its own capable of supplying 25% of global electricity usage. The corresponding drop in GHG emissions from the shutdown of coal, gas, and oil power plants would far outweigh the fact that part of the desert has been turned black.