https://en.wikipedia.org/wiki/Operation_Sunrise_(World_War_I... came close to a separate peace; I have a book I haven't finished about one of the negotiators, and it seems as if some sort of side deal might've been in progress but was blown up when soviet intelligence found out.
I don't have any strong evidence for this hypothesis; it's just the only one I've yet run across that (a) assumes Hitler to be rational*, but would still (b) explain how Hitler wound up in the bunker‡, when he'd already noted in his diary that Stalingrad meant his war plans (which had required not only Caucasian but also Iranian oil) were FUBAR.
It's certainly true that at the war's end, Nazi commanders were doing whatever they could to manage to surrender on the https://en.wikipedia.org/wiki/Operation_Paperclip side of things and not on the https://en.wikipedia.org/wiki/Operation_Osoaviakhim side.
If Hitler had been thinking the US and USSR were both interested in using the resources of the 3rd Reich against the other, he would have been correct: where he would've been wrong is in thinking he could cut a wholesale deal when they both wound up picking up most of what they wanted at retail.
* although after seeing Musk/TWTR play out, I'm a lot more open to the normally ludicrous idea that the top Nazis were a group of occult-addled meth-heads than I would've been 5 years ago...
cf https://en.wikipedia.org/wiki/Sportpalast_speech#Details
‡ I had assumed Downfall (2004) had been based on an autobiography I'd read because the events depicted meshed so closely (despite my initial scepticism as to the reliability of my source), but oddly I find no mention of that book on either en. or de.wikipedia...