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The most obvious application would be electrically controlled insulators.
If it's winter or summer, insulate the house.
But if outdoors is 72F (or 21C or another ideal temperature), let the ideal temperature into the house.
Temperature controlled crystal oscillators are another application IMO. Applications where we have a 'target temperature', and easy access to differing temperatures (ex inside the oven vs outside the oven vs the heat from a heater)