Room Temperature Superconductor Paper Retracted by Journal Nature
wsj.com
wsj.com
To the best of my knowledge no LK-99 paper got retracted simply because it didn't make it to publication.
I can see how one might make this compound, do some tests on it, and think "oh it's a superconductor" for a few months, but then surely they would do more tests to explore its properties and discover it's not a superconductor. Did they remain deliberately ignorant for 24 years?
My understanding is that they thought they'd detected signs that LK-99 would be superconducting, if they were able to come up with a process to synthesize it with sufficient purity. They spent 24 years (slowly, and without a lot of funding) trying to do that. And over the last couple of years, they started to convince themselves that they had succeeded.
The reproductions showed:
1. The ingredients commercially available have iron impurities. The oven baking process causes the iron to separate out, often towards the edges of the material chunks. Iron is ferromagnetic.
2. The LK99 material itself is strongly diamagnetic, which is interesting in and of itself, but obviously not world-changing.
The result of the combination of the above two is that the iron impurity is attracted to magnets, but the rest of the LK99 material is repelled. This makes samples "stand up", but not hover like a true superconductor would. All of the third-party reproductions showed this effect, none showed samples truly floating.
Similarly, the conductivity tests were zeroed badly. True superconductors have a step-change in conductivity, whereas the graphs measured by the korean team showed a rapid change followed by a slower gradual decrease. The lowest resistance they measured was still very high, comparable to metals, not superconductors.
This is a common issue with fringe research into superconductors: the "signal" they're looking for is a step-change in conductivity because it is easy to measure and rare in most normal materials. However, sudden conductivity changes can occur for all sorts of reasons. It's necessary, but not sufficient for superconductivity to be confirmed.
By reproduction, yes. By peer review, no.
The same can't be said for the other studies that come out and affect public policy which can't be reproduced. And in some cases we can't even get the data to attempt it!
Thanks for the explanation.
But wow, I'm kind of amazed at the simplicity of the error - iron impurities when you are testing for magnetism! I mean, who would have thought this could be a problem, before announcing this to the world?!
How strong is it's diamagnetic constant? Is it way more than pyrolytic carbon so that we can at least create fancy, levitating toys from it?