Instagram has a social network!? I must be missing something when I open their app. It seems like a "add a funny filter to your picture" sort of thing.
Roughly speaking, you might say:
Facebook: Social with everyone (polysocial?)
Path: Social with close friends (oligosocial?)
Pair: Social with your S.O. (monosocial?)
Twitter: Microsocial in text with everyone
Instagram: Microsocial in pictures (nanosocial? :P)
Having said that, I actually had a recent discussion with someone about how the heck they were going to monetize the service, and we didn't reeeally come up with a good suggestion aside from the expectable ads and premium filters.
Instagram: Microsocial with everyoneCouples like to hang out with other couples, so there might be revenue potential in the idea as well...