https://en.wikipedia.org/wiki/Asymmetric_multiprocessing
IIRC big.LITTLE implementations tended to have cores that didn't support the same instruction sets, meaning you couldn't migrate tasks between them if you needed to. Kind of like how laptops could switch between integrated and discrete GPUs, but some users would need to switch to the discrete GPU to use an external monitor even if they didn't want the power hit.
Also, "big.LITTLE" is a pretty strange brand name.