Basically, commissioners are usually former senior politicians who can no longer get elected, because they've been disgraced in some way or other. It's a sinecure.
It's almost impossible to dismiss them; the EU Parliament only has the power to dismiss the entire commission. That sounds like a nuclear option that could never be used; but is has been done, exactly once. It was over corruption; the parliament decided that essentially every commissioner was crooked.
No, after the European Parliament has approved the proposed President of the European Commission and the Council has chosen the other 26 commissioners, the Commission as a whole is subject to another vote of confidence by the European Parliament.
Each country sends candidates which then have to be approved by the european parliament.