Grungy rock music might only have a few instruments, but they're often purposefully highly distorted and have people pretty much screaming and shouting, leading to the actual sinal being closer to literally noise.
So the closer you are to literally noise, the less compressible your signal is.
Imagine a an image with a dozen sharp, clear, colorful squares. Now imagine a similar resolution image with only 5 colors, but they're different shapes and they're kind of fuzzy and they're really more like gradients instead of a pure color. Which is going to compress easier?
(FWIW, I’m way more of a punk fan myself, and usually find most classical music pretty boring.)
No, I do agree having multiple instruments does lead to a wider sound than just a single one. Plus multiple instruments will probably help balance out a single one being out of tune or not quite hitting the note right. But still, these instruments usually are way more tuned to produce closer to pure tones and their harmonic overtones than a guitar going through half a dozen different distortion and effect pedals then through a compressor along with a guy screaming all over the place into a microphone.
Also, when strumming a guitar you're almost always playing essentially six strings at once, playing a whole chord with only one instrument. Meanwhile on a flute or a trumpet or a clarinet or a violin a single player is only playing a single note at a time, a single string of the guitar. So during strumming sections a guitar is almost like 6 instruments, in terms of signal complexity. So a rhythm guitar strumming and a lead guitar picking strings is really almost like 7 instruments played by two people compared to many orchestral instruments.
Just look at these two spectrograms. Look at the rock song where there's a lot of distorted guitar, bass, drums, and singing going on and compare that to an active part of the classical recording. See how the classical recording has a lot more clean, straight lines while the rock song is a lot more fuzzy? Imagine if these were images, which would be more complicated to accurately compress? That's not really a great analogy, but it is touching on the same concept.
Rock song: https://youtu.be/BVsp23B8dWo?t=62
Classical song: https://youtu.be/Txp-pHU2K6w?t=210