Python is the definition of a general-purpose, beginner-friendly language that can also be used for more advanced stuff. That's part of what makes Python such a good CS101 language.
JavaScript is primarily a client-side language focused on interacting with web browsers and the DOM. This is starting to change with the advent of Node.js, but I would _not_ recommend jumping straight into Node style evented-IO if it's your first language.
http://www.youtube.com/playlist?list=PLEA1FEF17E1E5C0DA&...
Also this book:
http://learnpythonthehardway.org/book/
Javascript:
That said, Javascript is readily available (a runtime in your browser), so no additional installation steps are necessarily required to start. Javascript also follows C syntax patterns which also appear in a number of other languages whereas python is a bit unusual in the way it distinguishes code blocks (using indentation).
Either will work, I think that python is a bit more straightforward for your first few programs.
If you learn Python first, you might have trouble learning other languages.
Ideally, in the end it wont matter - a programmer can program in any language, but for starters I would say start with JavaScript.
I know, but sometimes 'esoteric' is better for beginning programmers. Compare the lesson on ternary operators:
some(blah) if 'a' in blah else blah
(blah.indexOf('a') != -1) ? some(blah) : blah;
For me learning Python first (Well, not first, but it was the first language I learned that wasn't like...qbasic or pascal or something nasty and dos-y like that - I started using Python circa 1.5.2 on an early G3 Mac) ruined just about every other language for me because, well, they're just all so much work. Python just stays out of your way so well 99% of the time, and it has the nicest (Not necessarily LARGEST, but best curated/most coherent) standard library of any language I've used.
That said, Scala (and Lift in particular) have been catching my eye lately - not quite as elegant (but with a few new tricks too...), but the performance characteristics are certainly appealing, which is the one area where python is...lacking.
Learn one, then learn the other - start where you want to.