EDIT: Here's a video of someone replicating the shots with that rifle. https://www.youtube.com/watch?v=ghmY6HmR4fs The comments also point out other factors that could have made the shot easier.
Also, the car only started accelerating after the hit was made, and it was fairly axial to the bullet trajectory. I dunno know about you, but I can reload a bolt action rifle without dropping aim in under a second. It’s using the rifle as it was designed to be used.
It wasn’t a good shot. It was a lucky shot. One he clearly didn’t fully prepare to land, otherwise he probably wouldn’t have been arrested shortly after in a nearby movie theater. It was hardly sophisticated, and its success hinged almost entirely on blind luck and circumstance, which is the most difficult scenario to protect against.