URL parsing semantics are defined by and dependent upon the scheme. (That's spec.) By definition, if you don't recognize the scheme, you cannot guarantee a correctly parsed URL. From RFC 1738:

The Internet Assigned Numbers Authority (IANA) will maintain a registry of URL schemes. Any submission of a new URL scheme must include a definition of an algorithm for accessing of resources within that scheme and the syntax for representing such a scheme.

The behavior described (extracting the scheme and treating the rest as an opaque string) is pretty much the only thing you can do when the scheme is unrecognized. (The other options being to throw an exception or return null.)

Based on the description, it sounds like neither are breaking spec—it's just that Node supports "postgres". That is, unless it's true that Node's URL implementation is supposed to match what browsers do, in which case Node is breaking spec—its own.