> All naturally occurring tungsten isotopes are expected to alpha decay into hafnium, but with extremely long lifetimes. Since the decay energies for all these decays are in the same energy range as beta and gamma backgrounds from the natural decay chains, their observation is a difficult task. Yet with cryogenic scintillator experiments, these backgrounds can be discriminated from the alpha signal, leading to a basically background free measurement of such alpha decays, see figure 13. Hence, the natural decay of W-180 was observed unambiguously for the first time.
Update: Apparently it was not the only rare decay detected during a dark matter experiment, in fact dark matter searches are a major source of rare decay detection. Previously in 2003, Bismuth-209's radioactivity was also detected as a bonus result of a dark matter search, with a half life of 10^19 years. [1] In 2019, the XENON1T experiment detected the radioactivity of Xenon-124 (again, because Xe was used inside the detector), with a half life of 10^22 years. By far it's the rarest radioactive decay ever directly observed by physicists [2].
[0] https://en.wikipedia.org/wiki/Cryogenic_Rare_Event_Search_wi...
[1] https://physicsworld.com/a/bismuth-breaks-half-life-record-f...
[2] https://en.wikipedia.org/wiki/Isotopes_of_xenon#Xenon-124