One takes between a few days and a few months. The other is a few years, unless you get pro training.
I guarantee most people starting with Python from another language will be productive quickly. But they will curse the packaging ecosystem because they will follow a lot of tutorials that don't follow this:
https://bitecode.substack.com/p/why-not-tell-people-to-simpl...
And they'll get screwed.
They will have a hard time learning this:
https://www.bitecode.dev/p/relieving-your-python-packaging-p...
It will take a long time of trials and errors, suffering all the way.
And this is true for many other aspects: good editor config, good web deployment story, good app sharing system, good tooling setup, etc
A runtime or a stlib is quite small and stable. But an ecosystem is gigantic and moving.