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I wear them all day during work and also then a couple hours in the evening without any issue. Pure bliss

I get pain from the hears not being in their natural position.

That problem went away for me once I found headphones that are actually over-ear and not only marketed as such. I can wear them all day every day because they're large enough to not even touch my ears, very light because of a plastic case and open headphones so they don't feel as "pressurized". Bad for noisy environments, though.

My hears are perpendicular from my head

It’s quite common. I own only open headphones due to this