Could be a skill issue on the part of the replicators? The russian anime girl scientist had to make a bunch of modifications (and was cursing the orig authors) before she could make her rocks float.
link?
What...
The mechanism is plausible - if the reaction actually proceeds by driving off the sulfate and substituting in the copper at high temperature, it's entirely possible the vacuum synthesis of the authors is unnecessary (I have in fact had personal experience with trying to replicate a paper where it turned out that a pretty important step was acting as an oxygen-diffusion rate-limiter, and this just...wasn't identified at all by the papers authors).
@iris_IGB = Random Russian anime girl scientist who synth'd in her apartment kitchen.