Glacier is a big "keep your lips sealed" one. I'd love AWS to talk about everything there, and the entire journey it was on because it is truly fascinating.
The original Glacier was very clearly tape, but given the instant retrieval capabilities the newer S3-Glacier tiers are most likely just low-margin HDDs, maybe with some dynamic powering on and off of drives/servers.
No idea how it's evolved over the years, so for all I know it's tape based these days.