Passkeys are wonderful for consumer use, because they're meant to enable your own ability to break glass, by backing up the credential to other devices. You can do this via iCloud (by default) or via things like Airdrop.
Technically, the devices you share this credential to, cannot provide "attestation" - attestation is the "proof" that the keypair was created by a specific device (like a Yubikey, Apple Machine, etc). Manufacturers (like Yubico) ship a keypair / certificate onboard your key, that can't be extracted. There are no external methods to interface with this keypair - granting admins high confidence this is a real Yubikey.
You can see where this starts to become a problem without attestation, and the ability to share the keys. Enterprises are not willing to inherit the risk of an airdroppable credential exposing access to a privileged employees' account. There is a non-risk of digital theft when it comes to a Yubikey.
Ultimately - passkeys can't even be used to unlock your machines, or servers. FIDO2 (more importantly, OS developers) have a long way to go before we're done with passwords for good.
Today, Yubikeys are filling this gap for most of the enterprise market, some of whom have spent multiple millions of dollars on hardware. Passkeys in their current state are going to be a hard sell.