Think of Tunneling or layers or nesting dolls. The order doesn't particularly matter from a security perspective. Though today I'd wrap with the conventional algorithm on the OUTSIDE layer, since it takes less computational time to check / validate. The inner layer would then be one or more of the post-quantum algorithms; a particularly paranoid application might use more than one if something absolutely must remain a secret.
So you’re encrypting with an asymmetric post quantum algorithm then using that as a payload with regular ED25519 or similar?
What value does the pre quantum wrapper add?
Post-quantum algorithms are, as yet, young and very possibly poorly understood. They may even offer no security at all (due to presently unseen flaws); therefore as a hedge against that include at least another currently in use and current best practice algorithm so that at least _that_ level of security is retained.
Plus, as I pointed out several replies ago, if the current (and fast since reasonable key size Elliptic Curve based) algorithm is the outer layer it can be validated quickly which is a better guard against denial of service attacks and other poor fakes.
Later
(Leaving this comment here in perpetuity as evidence that I didn't think about your question as hard as David Adrian did. The message still holds, and that message is: "big ol' shrug".)