Hybrid deployment (E.G. with ECC using a curve like 25519) is a great recommendation and probably obvious, far more so than picking a winner among the available post quantum possibly safe algorithms.
Later
(Leaving this comment here in perpetuity as evidence that I didn't think about your question as hard as David Adrian did. The message still holds, and that message is: "big ol' shrug".)
Think of Tunneling or layers or nesting dolls. The order doesn't particularly matter from a security perspective. Though today I'd wrap with the conventional algorithm on the OUTSIDE layer, since it takes less computational time to check / validate. The inner layer would then be one or more of the post-quantum algorithms; a particularly paranoid application might use more than one if something absolutely must remain a secret.
So you’re encrypting with an asymmetric post quantum algorithm then using that as a payload with regular ED25519 or similar?
What value does the pre quantum wrapper add?
Post-quantum algorithms are, as yet, young and very possibly poorly understood. They may even offer no security at all (due to presently unseen flaws); therefore as a hedge against that include at least another currently in use and current best practice algorithm so that at least _that_ level of security is retained.
Plus, as I pointed out several replies ago, if the current (and fast since reasonable key size Elliptic Curve based) algorithm is the outer layer it can be validated quickly which is a better guard against denial of service attacks and other poor fakes.
Edit: reference https://mailarchive.ietf.org/arch/msg/spasm/McksDhejGgJJ6xG6...
Unless there is an unexpected leap in the viability of quantum cryptanalysis, you should expect that all commercial/standard cryptography with PQ capabilities will run in a hybrid configuration.
I'm only commenting here because there's a pervasive belief that this is controversial in cryptography engineering circles, or that NIST is trying somehow to prevent hybrid schemes from happening, which is simply not the case --- though they may not bother to standardize any particular mechanism of combining ECC/RSA with PQ exchanges (but: they don't standardize stuff like TLS ciphersuites, either).
A conservative but reasonable risk assumption is to act as if all internet traffic prior to the year 2023 was transmitted in the clear. This includes Signal, PGP, and Tor.