Sure... you can also learn everything a Stanford class teaches online. You can find alternatives for the networking aspects, etc. Still... universities tend to be how people do this. You can bodybuild without a gym. Indomitable willpower & a DIY ethic are admirable, but "hacks" are still the way 90% of people get the job done.
I think you are downplaying how hard it is to be social, in various contexts. Alcohol can be used to dull pain. This definitely does occur frequently, especially once substance abuse is the pattern.
This does not negate the earlier comment about lubricating social interactions. That's generally the starting point for alcohol use. Flirting in high school. Being socially adventurous in college. Getting intimate with coworkers.
Substance mediated mind alteration is not new. It's not just escapism or "opium for the masses." There are many real reasons people use mind altering substances. Escapism & "opium for the masses," is, however, usually the mode when/once we're talking about addiction.
If you look at why alcoholics drink, and why high schoolers drink.... the reasons are just different.