Sorry, but that phrase really annoys me.[0] What does it actually mean?
[0] full disclosure: PhD in organic chemistry
Sorry, but that phrase really annoys me.[0] What does it actually mean?
[0] full disclosure: PhD in organic chemistry
These compounds are not literally "forever" but they have long half-lives once released into the environment, due to the strength of C-F bonds and due to pollutants partitioning into low-degradation-activity environments. For example, a certain compound may be degraded by ultraviolet light from sun exposure, but tend to adsorb to soil where it's shielded from light.
PFAS share a lot of characteristics with the earlier-known "persistent organic pollutants" like polychlorinated biphenyls:
- Polyhalogenated organic compounds
- Low acute toxicity
- Endocrine disruptor activity
- Low rate of natural breakdown in the environment
In fact PFAS of concern share so many characteristics with the historically known PoPs that I am not sure why they got their own phrase "forever chemicals." They don't actually seem to have longer half-lives than those PoPs known by the 1970s.
For further reading, here is a page on PFAS from the Stockholm Convention on Persistent Organic Pollutants:
https://chm.pops.int/Implementation/IndustrialPOPs/PFAS/Over...
And one from the Environmental Protection Agency:
But we choose to use it because a lot of people don't know the chemistry but recognize this label.