Thanks to Proton, most games work on Linux, as long as they don't have any anti-cheat rootkits.
And when looking at the top 20 most played games on Steam, there's some pretty big titles missing. PUBG (5th most played) is borked, CoD MWII (6th) is borked, Destiny 2 (9th) is borked, Rainbow Six Siege (10th) is borked, FIFA 23 (11th) is borked, NARAKA: BLADEPOINT (13th) is silver, Rust (14th) is bronze and Dead by Daylight (20th) is bronze. So when it comes to "most players", there's definitely a lot of gaps too.
I have a Steam Deck and I can have pretty good gaming experiences on it. Surprisingly even. But it's definitely not perfect, and one of the reasons why I can feel pretty confident in owning a Steam Deck is that I still have a Windows-based gaming PC that I can fall back on.