Start with EXPLAIN ANALYZE then work from there. You can use tools where you paste the output of it and it shows you the data in a more easy to understand format.
I am using https://explain.dalibo.com/ for that exact purpose and it does a great job highlighting the perfs issues.
I don't have any other good recommendations other than learning how to read and use EXPLAIN [1]. This should typically be the first tool when you have a slow query.