Any advice for high school students who don't have Upperclassman to look up to for advice?
The "Who's Hiring" monthly threads are a good place to start looking.
When I was at FB, several of the interns had just finished high school, so it's certainly doable to get a top company offer - same goes for start-ups. It's just a question of emailing them and having the experience - past projects, etc - to be interesting. Same advice as I'd give to a college student.